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Previous year Question Paper (PYQ)-Lecturer (Non Technical) in CHEMISTRY-2023, DTE ASSAM exam| ASERB Exam

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Brinjal Sabji recipe

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Application of CFT

  APPLICATIONS OF CRYSTAL FIELD THEORY Crystal field theory was developed by Hans Bethe(1929) and Van Vleck(1935). This theory ( CFT ) largely replaced Valence Bond Theory for interpreting the chemistry of coordination compounds. Main assumptions in CFT, ·          According to CFT, the interactions between the central metal ion and its ligands are purely electrostatic (ionic). ·          The ligands are treated as point Charges. ·          If the ligand is anionic : ion-ion interaction. If the ligand is neutral : ion-dipole interaction ·          The electrons on metal occupy those d-orbitals farthest away from the direction of approach of ligands. Three p - orbitals Five d - orbitals In octahedral field: dxy, dxz, dyz ▬ t 2g set dz², dx²-y² ▬ e g set Applications of CFT are, 1.    ...